Detailed Outcrop Gamma-Ray Characterization of the Woodford Shale, South-central Oklahoma

Alischa M. Krystyniak, School of Geology, Oklahoma State University, Stillwater, OK 74078, phone: 405-744-6358, akglaciergirl2003@yahoo.com, Stanley T. Paxton, School of Geology, Oklahoma State University, 105 Noble Research Center, Stillwater, OK 74078, and William S. Coffey, Devon Energy Corporation, 20 N. Broadway Suite 1500, Oklahoma City, OK 73102-8260.

Detailed outcrop gamma-ray characterization of the Woodford Shale, south-central Oklahoma.

The Devonian - Mississippian Woodford Shale of Oklahoma is a hydrocarbon-prone source rock that contains a heterogeneous mix of lithofacies with marine affinities. We are currently constructing detailed lithofacies profiles and measuring the spectral gamma-ray response in outcrop. Outcrops vary in thickness from about 30 to 150 m. The intent of this work is to provide documentation for the variations in gamma-ray response relative to the different lithofacies. Lithofacies recognized to date include black, highly fissile paper shale, black siliceous shale, gray/brown shale, intervals of shale containing phosphate nodules, some chert layers, and rare limestone.

TOC, XRD, whole rock chemistry, and thin-section data are being collected from each of the lithofacies in order to more fully document the controls on gamma-ray response. Relative to potassium and thorium, uranium is responsible for the bulk of the variation in outcrop gamma-ray response. Gamma-ray readings in Carter and Murray Counties have values of uranium that range from 7 to 80 ppm. Paper shales tend to have the highest concentrations of uranium. XRD reveals that the Woodford contains a high percentage of illite and mixed-layered illite / smectite. Thin sections show that the quartz in the siliceous shale is both detrital silt and diagenetic chert. Some packages of the Woodford appear to contain alternating layers, 2-3 cm in thickness, of highly paper shale with siliceous shale. API gamma-ray values, calculated using a standard equation and plotted with the vertical lithofacies descriptions, reveal characteristic “finger-prints” for each of the lithofacies.